A novel bonding mode of oximato ligand to a metal; synthesis and X-ray crystal structure of bis[acetone oximatobis(cyclopentadienyl)gadolinium] [{(C5H5)2Gd(μ-η2-ONCMe 2)}2]

Zhongzhi Wu, Xigen Zhou, Wei Zhang, Zheng Xu, Xiaozeng You, Xiaoying Huang

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Reaction of [Cp3Gd] (Cp = C5H5) with acetone oxime in THF at room temp. results in the formation of a new complex [{Cp2Gd(μ-η2-ONCMe2)}2]; X-ray analysis shows an unusual structure with the O-N fragment of ONCMe 2 ligand acting as both a bridging and side-on donating group.

Original languageEnglish (US)
Pages (from-to)813-814
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
DOIs
StatePublished - Dec 1 1994

Fingerprint

Gadolinium
X ray analysis
Acetone
Crystal structure
Metals
Ligands
X-Rays
X rays
acetoxime
Oximes

All Science Journal Classification (ASJC) codes

  • Molecular Medicine

Cite this

@article{121dce7c0a834f8e86d91c35d46fcf62,
title = "A novel bonding mode of oximato ligand to a metal; synthesis and X-ray crystal structure of bis[acetone oximatobis(cyclopentadienyl)gadolinium] [{(C5H5)2Gd(μ-η2-ONCMe 2)}2]",
abstract = "Reaction of [Cp3Gd] (Cp = C5H5) with acetone oxime in THF at room temp. results in the formation of a new complex [{Cp2Gd(μ-η2-ONCMe2)}2]; X-ray analysis shows an unusual structure with the O-N fragment of ONCMe 2 ligand acting as both a bridging and side-on donating group.",
author = "Zhongzhi Wu and Xigen Zhou and Wei Zhang and Zheng Xu and Xiaozeng You and Xiaoying Huang",
year = "1994",
month = "12",
day = "1",
doi = "10.1039/C39940000813",
language = "English (US)",
pages = "813--814",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "7",

}

TY - JOUR

T1 - A novel bonding mode of oximato ligand to a metal; synthesis and X-ray crystal structure of bis[acetone oximatobis(cyclopentadienyl)gadolinium] [{(C5H5)2Gd(μ-η2-ONCMe 2)}2]

AU - Wu, Zhongzhi

AU - Zhou, Xigen

AU - Zhang, Wei

AU - Xu, Zheng

AU - You, Xiaozeng

AU - Huang, Xiaoying

PY - 1994/12/1

Y1 - 1994/12/1

N2 - Reaction of [Cp3Gd] (Cp = C5H5) with acetone oxime in THF at room temp. results in the formation of a new complex [{Cp2Gd(μ-η2-ONCMe2)}2]; X-ray analysis shows an unusual structure with the O-N fragment of ONCMe 2 ligand acting as both a bridging and side-on donating group.

AB - Reaction of [Cp3Gd] (Cp = C5H5) with acetone oxime in THF at room temp. results in the formation of a new complex [{Cp2Gd(μ-η2-ONCMe2)}2]; X-ray analysis shows an unusual structure with the O-N fragment of ONCMe 2 ligand acting as both a bridging and side-on donating group.

UR - http://www.scopus.com/inward/record.url?scp=37049089384&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049089384&partnerID=8YFLogxK

U2 - 10.1039/C39940000813

DO - 10.1039/C39940000813

M3 - Article

SP - 813

EP - 814

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 7

ER -