Application of 1,2:5,6-di-O-cyclohexylidene-D-mannitol as the chiral director in Matteson's asymmetric homologation

Guisheng Li, George Kabalka

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

1,2:5,6-Di-O-cyclohexylidene-D-mannitol is the good chiral director in Matteson's asymmetric homologation as indicated by the high enantiomeric excesses (ee's) of the secondary alcohols produced by treatment of the homologation products with alkyllithium or Grignard reagents followed by oxidation.

Original languageEnglish (US)
Pages (from-to)66-69
Number of pages4
JournalJournal of Organometallic Chemistry
Volume581
Issue number1-2
DOIs
StatePublished - Jun 5 1999
Externally publishedYes

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mannitol
Mannitol
reagents
alcohols
Alcohols
Oxidation
oxidation
products

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Application of 1,2:5,6-di-O-cyclohexylidene-D-mannitol as the chiral director in Matteson's asymmetric homologation. / Li, Guisheng; Kabalka, George.

In: Journal of Organometallic Chemistry, Vol. 581, No. 1-2, 05.06.1999, p. 66-69.

Research output: Contribution to journalArticle

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