Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds

Prem C. Srivastava, Furn F. Knapp, George Kabalka, Sastry A. Kunda

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkyl vinyl mercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkyl vinyl iodides. These method are also efficient for the synthesis of the corresponding radioiodinated compounds.

Original languageEnglish (US)
Pages (from-to)355-364
Number of pages10
JournalSynthetic Communications
Volume15
Issue number4
DOIs
StatePublished - Mar 1 1985
Externally publishedYes

Fingerprint

Trifluoroacetic Acid
Iodides
Acids
Mercury
Oxidation
Substrates
vinyl iodide
chloramine-T

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds. / Srivastava, Prem C.; Knapp, Furn F.; Kabalka, George; Kunda, Sastry A.

In: Synthetic Communications, Vol. 15, No. 4, 01.03.1985, p. 355-364.

Research output: Contribution to journalArticle

Srivastava, Prem C. ; Knapp, Furn F. ; Kabalka, George ; Kunda, Sastry A. / Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds. In: Synthetic Communications. 1985 ; Vol. 15, No. 4. pp. 355-364.
@article{d4612289660046928d50f8f33bb072fe,
title = "Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds",
abstract = "Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkyl vinyl mercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkyl vinyl iodides. These method are also efficient for the synthesis of the corresponding radioiodinated compounds.",
author = "Srivastava, {Prem C.} and Knapp, {Furn F.} and George Kabalka and Kunda, {Sastry A.}",
year = "1985",
month = "3",
day = "1",
doi = "10.1080/00397918508063810",
language = "English (US)",
volume = "15",
pages = "355--364",
journal = "Synthetic Communications",
issn = "0039-7911",
publisher = "Taylor and Francis Ltd.",
number = "4",

}

TY - JOUR

T1 - Facile-radioiododemetallation reactions for the convenient preparation of radioiodinated compounds

AU - Srivastava, Prem C.

AU - Knapp, Furn F.

AU - Kabalka, George

AU - Kunda, Sastry A.

PY - 1985/3/1

Y1 - 1985/3/1

N2 - Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkyl vinyl mercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkyl vinyl iodides. These method are also efficient for the synthesis of the corresponding radioiodinated compounds.

AB - Several new methods for the preparation of vinyl iodides via mercuration and thallation reactions of vinylboronic acids have been explored. Chloramine-T oxidation of alkyl vinyl mercury iodides or iodide treatment of alkylvinylthallium trifluoroacetate substrates, prepared from the corresponding alkylvinylboronic acid and thallic trifluoroacetate, yields the corresponding alkyl vinyl iodides. These method are also efficient for the synthesis of the corresponding radioiodinated compounds.

UR - http://www.scopus.com/inward/record.url?scp=84889282244&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84889282244&partnerID=8YFLogxK

U2 - 10.1080/00397918508063810

DO - 10.1080/00397918508063810

M3 - Article

VL - 15

SP - 355

EP - 364

JO - Synthetic Communications

JF - Synthetic Communications

SN - 0039-7911

IS - 4

ER -