Generation of cations from alkoxides

Allylation of propargyl alcohols

George Kabalka, Min Liang Yao, Scott Borella

Research output: Contribution to journalArticle

48 Citations (Scopus)

Abstract

The reaction of alkoxides with boron trichloride results in the generation of cations in the absence of Brønsted acids. The absence of a Brønsted acid can make a difference in subsequent transformations such as allylation reactions.

Original languageEnglish (US)
Pages (from-to)11320-11321
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number35
DOIs
StatePublished - Sep 6 2006
Externally publishedYes

Fingerprint

Allylation
Cations
Alcohols
Positive ions
Acids
Boron
propargyl alcohol

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Generation of cations from alkoxides : Allylation of propargyl alcohols. / Kabalka, George; Yao, Min Liang; Borella, Scott.

In: Journal of the American Chemical Society, Vol. 128, No. 35, 06.09.2006, p. 11320-11321.

Research output: Contribution to journalArticle

Kabalka, George ; Yao, Min Liang ; Borella, Scott. / Generation of cations from alkoxides : Allylation of propargyl alcohols. In: Journal of the American Chemical Society. 2006 ; Vol. 128, No. 35. pp. 11320-11321.
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