Investigation of the behavior of arenediazonium salts with olefins in BmimPF6

George Kabalka, Gang Dong, Bollu Venkataiah

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

The palladium-catalyzed reactions of olefins with arenediazonium salts in ionic liquids were investigated. For methyl acrylate and methyl acrylonitrile, normal Heck cross-coupling products are obtained in good yields. However, highly selective dimerization products are formed in excellent yields for styrenes. The catalyst system can be recycled.

Original languageEnglish (US)
Pages (from-to)2775-2777
Number of pages3
JournalTetrahedron Letters
Volume45
Issue number13
DOIs
StatePublished - Mar 22 2004
Externally publishedYes

Fingerprint

Styrenes
Acrylonitrile
Ionic Liquids
Dimerization
Palladium
Alkenes
Salts
Catalysts
methyl acrylate

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Investigation of the behavior of arenediazonium salts with olefins in BmimPF6. / Kabalka, George; Dong, Gang; Venkataiah, Bollu.

In: Tetrahedron Letters, Vol. 45, No. 13, 22.03.2004, p. 2775-2777.

Research output: Contribution to journalArticle

Kabalka, George ; Dong, Gang ; Venkataiah, Bollu. / Investigation of the behavior of arenediazonium salts with olefins in BmimPF6. In: Tetrahedron Letters. 2004 ; Vol. 45, No. 13. pp. 2775-2777.
@article{6a8debf689eb4a03b307553349f4b84a,
title = "Investigation of the behavior of arenediazonium salts with olefins in BmimPF6",
abstract = "The palladium-catalyzed reactions of olefins with arenediazonium salts in ionic liquids were investigated. For methyl acrylate and methyl acrylonitrile, normal Heck cross-coupling products are obtained in good yields. However, highly selective dimerization products are formed in excellent yields for styrenes. The catalyst system can be recycled.",
author = "George Kabalka and Gang Dong and Bollu Venkataiah",
year = "2004",
month = "3",
day = "22",
doi = "10.1016/j.tetlet.2004.02.023",
language = "English (US)",
volume = "45",
pages = "2775--2777",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "13",

}

TY - JOUR

T1 - Investigation of the behavior of arenediazonium salts with olefins in BmimPF6

AU - Kabalka, George

AU - Dong, Gang

AU - Venkataiah, Bollu

PY - 2004/3/22

Y1 - 2004/3/22

N2 - The palladium-catalyzed reactions of olefins with arenediazonium salts in ionic liquids were investigated. For methyl acrylate and methyl acrylonitrile, normal Heck cross-coupling products are obtained in good yields. However, highly selective dimerization products are formed in excellent yields for styrenes. The catalyst system can be recycled.

AB - The palladium-catalyzed reactions of olefins with arenediazonium salts in ionic liquids were investigated. For methyl acrylate and methyl acrylonitrile, normal Heck cross-coupling products are obtained in good yields. However, highly selective dimerization products are formed in excellent yields for styrenes. The catalyst system can be recycled.

UR - http://www.scopus.com/inward/record.url?scp=1542298830&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1542298830&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2004.02.023

DO - 10.1016/j.tetlet.2004.02.023

M3 - Article

AN - SCOPUS:1542298830

VL - 45

SP - 2775

EP - 2777

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 13

ER -