Iodination of organotrifluoroborates

Synthesis of vinyl and alkynyl iodides

George Kabalka, Arjun Reddy Mereddy

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Vinyl- and alkynyltrifluoroborates are rapidly converted to vinyl and alkynyl iodides under mild conditions using sodium iodide in the presence of chloramine-T. The reaction is stereospecific and proceeds in excellent yield.

Original languageEnglish (US)
Pages (from-to)1417-1419
Number of pages3
JournalTetrahedron Letters
Volume45
Issue number7
DOIs
StatePublished - Feb 9 2004
Externally publishedYes

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Sodium Iodide
Halogenation
chloramine-T
vinyl iodide

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Iodination of organotrifluoroborates : Synthesis of vinyl and alkynyl iodides. / Kabalka, George; Mereddy, Arjun Reddy.

In: Tetrahedron Letters, Vol. 45, No. 7, 09.02.2004, p. 1417-1419.

Research output: Contribution to journalArticle

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