Iron trichloride mediated allylation of lithium alkoxides through an unusual carbon-oxygen bond cleavage

George Kabalka, Min Liang Yao, Scott Borella, Laura K. Goins

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

Iron trichloride was found to cleave carbon-oxygen bonds in a variety of lithium alkoxides at room temperature. Other Lewis acids were also found to cleave the alkoxides. Acidsensitive groups are tolerated under the reported reaction conditions.

Original languageEnglish (US)
Pages (from-to)4112-4114
Number of pages3
JournalOrganometallics
Volume26
Issue number17
DOIs
StatePublished - Aug 13 2007
Externally publishedYes

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Allylation
Lewis Acids
alkoxides
Lithium
cleavage
Carbon
Iron
lithium
chlorides
Oxygen
iron
carbon
oxygen
Temperature
acids
room temperature

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Iron trichloride mediated allylation of lithium alkoxides through an unusual carbon-oxygen bond cleavage. / Kabalka, George; Yao, Min Liang; Borella, Scott; Goins, Laura K.

In: Organometallics, Vol. 26, No. 17, 13.08.2007, p. 4112-4114.

Research output: Contribution to journalArticle

Kabalka, George ; Yao, Min Liang ; Borella, Scott ; Goins, Laura K. / Iron trichloride mediated allylation of lithium alkoxides through an unusual carbon-oxygen bond cleavage. In: Organometallics. 2007 ; Vol. 26, No. 17. pp. 4112-4114.
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