Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2

Zhong Zhi Wu, Zu En Huang, Rui Fang Cai, Xi Geng Zhou, Zheng Xu, Xiao Zeng You, Xiao Ying Huang

Research output: Contribution to journalArticle

Abstract

The complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2 has been studied by X-ray crystallography. The crystal is orthorhombic, space group Phcn with a = 20. 414 (2), b = 9. 548(1), c = 16. 390(6) Å. V = 3194. 9(6) Å3, Mr = 849. 46, Z = 4, Dc= 1. 77 g/cm3, F(000) = 1664, μ = 46. 37 cm-1. The Tb3+ ion is coordinated by two CH3C5H4 groups, two chloride ions and one oxygen atom from tetrahydrofuran to form a distorted trigonal bipyramidal geometry. Two bridging Tb - Cl bond lengths are 2. 716(2) and 2-790(2) Å, respectively. The Tb - O(THF) and average Tb - C (CH3C5H4) bond lengths are 2. 559(6) and 2. 670(4) Å, respectively.

Original languageEnglish (US)
JournalJiegou Huaxue
Volume15
Issue number5
StatePublished - Dec 1 1996

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Bond length
Molecular structure
Ions
X ray crystallography
Chlorides
Oxygen
Atoms
Crystals
Geometry
tetrahydrofuran

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Wu, Z. Z., Huang, Z. E., Cai, R. F., Zhou, X. G., Xu, Z., You, X. Z., & Huang, X. Y. (1996). Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2. Jiegou Huaxue, 15(5).

Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2. / Wu, Zhong Zhi; Huang, Zu En; Cai, Rui Fang; Zhou, Xi Geng; Xu, Zheng; You, Xiao Zeng; Huang, Xiao Ying.

In: Jiegou Huaxue, Vol. 15, No. 5, 01.12.1996.

Research output: Contribution to journalArticle

Wu, ZZ, Huang, ZE, Cai, RF, Zhou, XG, Xu, Z, You, XZ & Huang, XY 1996, 'Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2', Jiegou Huaxue, vol. 15, no. 5.
Wu ZZ, Huang ZE, Cai RF, Zhou XG, Xu Z, You XZ et al. Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2. Jiegou Huaxue. 1996 Dec 1;15(5).
Wu, Zhong Zhi ; Huang, Zu En ; Cai, Rui Fang ; Zhou, Xi Geng ; Xu, Zheng ; You, Xiao Zeng ; Huang, Xiao Ying. / Molecular structure of organolanthanide complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2. In: Jiegou Huaxue. 1996 ; Vol. 15, No. 5.
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AU - Cai, Rui Fang

AU - Zhou, Xi Geng

AU - Xu, Zheng

AU - You, Xiao Zeng

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N2 - The complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2 has been studied by X-ray crystallography. The crystal is orthorhombic, space group Phcn with a = 20. 414 (2), b = 9. 548(1), c = 16. 390(6) Å. V = 3194. 9(6) Å3, Mr = 849. 46, Z = 4, Dc= 1. 77 g/cm3, F(000) = 1664, μ = 46. 37 cm-1. The Tb3+ ion is coordinated by two CH3C5H4 groups, two chloride ions and one oxygen atom from tetrahydrofuran to form a distorted trigonal bipyramidal geometry. Two bridging Tb - Cl bond lengths are 2. 716(2) and 2-790(2) Å, respectively. The Tb - O(THF) and average Tb - C (CH3C5H4) bond lengths are 2. 559(6) and 2. 670(4) Å, respectively.

AB - The complex [(η5-CH3C5H4) 2Tb(μ-Cl) (THF)]2 has been studied by X-ray crystallography. The crystal is orthorhombic, space group Phcn with a = 20. 414 (2), b = 9. 548(1), c = 16. 390(6) Å. V = 3194. 9(6) Å3, Mr = 849. 46, Z = 4, Dc= 1. 77 g/cm3, F(000) = 1664, μ = 46. 37 cm-1. The Tb3+ ion is coordinated by two CH3C5H4 groups, two chloride ions and one oxygen atom from tetrahydrofuran to form a distorted trigonal bipyramidal geometry. Two bridging Tb - Cl bond lengths are 2. 716(2) and 2-790(2) Å, respectively. The Tb - O(THF) and average Tb - C (CH3C5H4) bond lengths are 2. 559(6) and 2. 670(4) Å, respectively.

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