Palladium-catalyzed regio- And stereoselective cross-coupling of Baylis-Hillman adducts and bimetals

A novel method for the synthesis of substituted allylsilanes and allylgermanes

George Kabalka, Bollu Venkataiah, Gang Dong

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Cross-coupling reactions between Baylis-Hill-man acetate adducts and bimetallic reagents (Si-Si, Ge-Ge) catalyzed by a phosphine-free palladium complex are described. 3-Substituted-2-carbonylallylsilanes and allylgermanes were isolated in high yields. The cross-coupling reactions are regio- and stereoselective.

Original languageEnglish (US)
Pages (from-to)762-764
Number of pages3
JournalOrganometallics
Volume24
Issue number4
DOIs
StatePublished - Feb 14 2005
Externally publishedYes

Fingerprint

phosphine
bimetals
Bimetals
cross coupling
Palladium
adducts
palladium
Acetates
synthesis
phosphines
reagents
acetates
allylsilane
2-propenylgermane

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

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abstract = "Cross-coupling reactions between Baylis-Hill-man acetate adducts and bimetallic reagents (Si-Si, Ge-Ge) catalyzed by a phosphine-free palladium complex are described. 3-Substituted-2-carbonylallylsilanes and allylgermanes were isolated in high yields. The cross-coupling reactions are regio- and stereoselective.",
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AU - Venkataiah, Bollu

AU - Dong, Gang

PY - 2005/2/14

Y1 - 2005/2/14

N2 - Cross-coupling reactions between Baylis-Hill-man acetate adducts and bimetallic reagents (Si-Si, Ge-Ge) catalyzed by a phosphine-free palladium complex are described. 3-Substituted-2-carbonylallylsilanes and allylgermanes were isolated in high yields. The cross-coupling reactions are regio- and stereoselective.

AB - Cross-coupling reactions between Baylis-Hill-man acetate adducts and bimetallic reagents (Si-Si, Ge-Ge) catalyzed by a phosphine-free palladium complex are described. 3-Substituted-2-carbonylallylsilanes and allylgermanes were isolated in high yields. The cross-coupling reactions are regio- and stereoselective.

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