Protonation of Acyllithium Reagents by Dichloromethane and Dichloroarylmethane

A New Method for the Synthesis of α,α-Dichloro Alcohols

George Kabalka, Nan Sheng Li, Su Yu

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The first example of the protonation of acyl- lithium reagents by dichloromethane and dichloroarylmethane is described. The reaction affords the corresponding α,α-dichloro alcohols in excellent yields.

Original languageEnglish (US)
Pages (from-to)1565-1566
Number of pages2
JournalOrganometallics
Volume14
Issue number4
DOIs
StatePublished - Jan 1 1995
Externally publishedYes

Fingerprint

Methylene Chloride
Protonation
Lithium
reagents
alcohols
lithium
Alcohols
synthesis

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Protonation of Acyllithium Reagents by Dichloromethane and Dichloroarylmethane : A New Method for the Synthesis of α,α-Dichloro Alcohols. / Kabalka, George; Li, Nan Sheng; Yu, Su.

In: Organometallics, Vol. 14, No. 4, 01.01.1995, p. 1565-1566.

Research output: Contribution to journalArticle

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abstract = "The first example of the protonation of acyl- lithium reagents by dichloromethane and dichloroarylmethane is described. The reaction affords the corresponding α,α-dichloro alcohols in excellent yields.",
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