Reaction of Organic Molecules on Solid Surfaces. 1. Facile Deuteration of Active Methylene Compounds with D2O-Treated Alumina

George Kabalka, Richard M. Pagni, Paula Bridwell, Elaine Walsh, Hamdi M. Hassaneen

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A procedure has been developed for the preparation of deuterated alumina. Treatment of ketones, active methylene compounds, and acidic hydrocarbons with this solid resulted in the deuteration of the compounds at acidic sites. Deuterated molecular sieves are also effective in these deuterations.

Original languageEnglish (US)
Pages (from-to)1513-1514
Number of pages2
JournalJournal of Organic Chemistry
Volume46
Issue number7
DOIs
StatePublished - Jan 1 1981

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Aluminum Oxide
Molecular sieves
Hydrocarbons
Ketones
Molecules

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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Reaction of Organic Molecules on Solid Surfaces. 1. Facile Deuteration of Active Methylene Compounds with D2O-Treated Alumina. / Kabalka, George; Pagni, Richard M.; Bridwell, Paula; Walsh, Elaine; Hassaneen, Hamdi M.

In: Journal of Organic Chemistry, Vol. 46, No. 7, 01.01.1981, p. 1513-1514.

Research output: Contribution to journalArticle

Kabalka, George ; Pagni, Richard M. ; Bridwell, Paula ; Walsh, Elaine ; Hassaneen, Hamdi M. / Reaction of Organic Molecules on Solid Surfaces. 1. Facile Deuteration of Active Methylene Compounds with D2O-Treated Alumina. In: Journal of Organic Chemistry. 1981 ; Vol. 46, No. 7. pp. 1513-1514.
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