Reaction of Organoboranes with Olefinic α, β-Unsaturated Nitro Compounds

George Kabalka, Yuan Zhu Gai, Naganna M. Goudgaon, Rajender S. Varma, Eugene E. Gooch

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The reaction of lithium triethylborohydride with nitroalkenes in the presence of borane results in the unexpected formation of N-ethylamine derivatives. Evidence supports a reaction sequence involving the 1, 2-addition of triethylborane to a nitroso intermediate.

Original languageEnglish (US)
Pages (from-to)493-495
Number of pages3
JournalOrganometallics
Volume7
Issue number2
DOIs
StatePublished - Feb 1 1988
Externally publishedYes

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Nitro Compounds
Boranes
nitro compounds
Lithium
Derivatives
boranes
lithium
triethylborane
ethylamine

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Reaction of Organoboranes with Olefinic α, β-Unsaturated Nitro Compounds. / Kabalka, George; Gai, Yuan Zhu; Goudgaon, Naganna M.; Varma, Rajender S.; Gooch, Eugene E.

In: Organometallics, Vol. 7, No. 2, 01.02.1988, p. 493-495.

Research output: Contribution to journalArticle

Kabalka, George ; Gai, Yuan Zhu ; Goudgaon, Naganna M. ; Varma, Rajender S. ; Gooch, Eugene E. / Reaction of Organoboranes with Olefinic α, β-Unsaturated Nitro Compounds. In: Organometallics. 1988 ; Vol. 7, No. 2. pp. 493-495.
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