Sodium perborate

A convenient reagent for benzylic hydroperoxide rearrangement

George Kabalka, N. Kesavulu Reddy, Chatla Narayana

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Sodium perborate in boron trifluoride etherate has been found to be an effective reagent for the hydroperoxide rearrangement of electron rich and highly substituted benzylic tertiary alcohols to phenols in good yields.

Original languageEnglish (US)
Pages (from-to)7667-7668
Number of pages2
JournalTetrahedron Letters
Volume34
Issue number48
DOIs
StatePublished - Nov 26 1993
Externally publishedYes

Fingerprint

sodium perborate
Phenols
Hydrogen Peroxide
Alcohols
Electrons
boron trifluoride etherate

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Sodium perborate : A convenient reagent for benzylic hydroperoxide rearrangement. / Kabalka, George; Kesavulu Reddy, N.; Narayana, Chatla.

In: Tetrahedron Letters, Vol. 34, No. 48, 26.11.1993, p. 7667-7668.

Research output: Contribution to journalArticle

Kabalka, George ; Kesavulu Reddy, N. ; Narayana, Chatla. / Sodium perborate : A convenient reagent for benzylic hydroperoxide rearrangement. In: Tetrahedron Letters. 1993 ; Vol. 34, No. 48. pp. 7667-7668.
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abstract = "Sodium perborate in boron trifluoride etherate has been found to be an effective reagent for the hydroperoxide rearrangement of electron rich and highly substituted benzylic tertiary alcohols to phenols in good yields.",
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