Synthesis and air stability of mixed ligand lanthanide organometallics involving both indenyl and cyclopentadienyl ligands

Zhou Zhennan, Zhongzhi Wu, Du Baohu, Ye Zhongwen

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

By the reaction of CP2LnCl (CP = C5H5; Ln = Sm, Dy, Ho, Er, Yb) with IndNa (Ind = C9H7), five new organolanthanides containing Cp and Ind groups have been synthesized. Comparing their air stability by exposure to air, we found these complexes were more stable in air than the corresponding CP3Ln, and their relative stability increased with a decrease of the metal ionic radii. All the complexes were characterized on the basis of their analytical and spectral data.

Original languageEnglish (US)
Pages (from-to)17-20
Number of pages4
JournalPolyhedron
Volume8
Issue number1
DOIs
StatePublished - Jan 1 1989

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Lanthanoid Series Elements
Organometallics
Rare earth elements
Ligands
ligands
air
synthesis
Air
Metals
radii
metals

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Synthesis and air stability of mixed ligand lanthanide organometallics involving both indenyl and cyclopentadienyl ligands. / Zhennan, Zhou; Wu, Zhongzhi; Baohu, Du; Zhongwen, Ye.

In: Polyhedron, Vol. 8, No. 1, 01.01.1989, p. 17-20.

Research output: Contribution to journalArticle

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