Synthesis and characterization of tantalum silyl and disilyl imido complexes that do not contain anionic π-ligands

Zhongzhi Wu, Ziling Xue

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

A series of Cp-free d0 silyl alkyl, alkylidene, alkylidyne, amide and related complexes were prepared and their chemistry was studied. The synthesis of a Cp-free Ta imido silyl and a Cp-free Ta imido disilyl complex is described. X-ray crystal structure of the compounds show a pseudotetrahedral arrangement in the Ta moiety with different bond angles.

Original languageEnglish (US)
Pages (from-to)4191-4192
Number of pages2
JournalOrganometallics
Volume19
Issue number21
DOIs
StatePublished - Oct 1 2000

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alkylidene
Tantalum
tantalum
Amides
amides
Crystal structure
chemistry
Ligands
X rays
ligands
crystal structure
synthesis
x rays

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Synthesis and characterization of tantalum silyl and disilyl imido complexes that do not contain anionic π-ligands. / Wu, Zhongzhi; Xue, Ziling.

In: Organometallics, Vol. 19, No. 21, 01.10.2000, p. 4191-4192.

Research output: Contribution to journalArticle

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