Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

Li Yong, Min Liang Yao, David Blevins, George Kabalka

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature. No additional oxidizing agent, base, or phosphine ligands are required. This journal is

Original languageEnglish (US)
Pages (from-to)4759-4764
Number of pages6
JournalDalton Transactions
Volume44
Issue number10
DOIs
StatePublished - Mar 14 2015
Externally publishedYes

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phosphine
Palladium
Polyethylene glycols
Oxidants
Ligands
Water
Air
Temperature
palladium(II) acetate

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions. / Yong, Li; Yao, Min Liang; Blevins, David; Kabalka, George.

In: Dalton Transactions, Vol. 44, No. 10, 14.03.2015, p. 4759-4764.

Research output: Contribution to journalArticle

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