The Reaction of Organic Molecules on Solid Surfaces. 2. An Efficient Method for the Preparation of Deuterated Alumina

Kevan Gaetano, Richard M. Pagni, George Kabalka, Paula Bridwell Elaine Walsh, Jeffrey True, Marilyn Underwood

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The construction and use of a simple and inexpensive device for the deuteration of alumina is described. Two methods are present for analyzing the extent of deuterating the solid: 1H NMR analysis of the water of dehydration and 1H NMR analysis of the phenylacetylene equilibrated with the solid. A theory is presented which should prove helpful in finding the optimum conditions for the preparation of the solid catalyst. When phenylacetylene is used as a model substrate, chromatographic and slurry methods for the deuteration of acidic organic molecules are compared.

Original languageEnglish (US)
Pages (from-to)499-502
Number of pages4
JournalJournal of Organic Chemistry
Volume50
Issue number4
DOIs
StatePublished - Jan 1 1985
Externally publishedYes

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Aluminum Oxide
Molecules
Nuclear magnetic resonance
Dehydration
Catalysts
Water
Substrates
phenylacetylene

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

The Reaction of Organic Molecules on Solid Surfaces. 2. An Efficient Method for the Preparation of Deuterated Alumina. / Gaetano, Kevan; Pagni, Richard M.; Kabalka, George; Elaine Walsh, Paula Bridwell; True, Jeffrey; Underwood, Marilyn.

In: Journal of Organic Chemistry, Vol. 50, No. 4, 01.01.1985, p. 499-502.

Research output: Contribution to journalArticle

Gaetano, Kevan ; Pagni, Richard M. ; Kabalka, George ; Elaine Walsh, Paula Bridwell ; True, Jeffrey ; Underwood, Marilyn. / The Reaction of Organic Molecules on Solid Surfaces. 2. An Efficient Method for the Preparation of Deuterated Alumina. In: Journal of Organic Chemistry. 1985 ; Vol. 50, No. 4. pp. 499-502.
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