Use of organoboron halides in organic synthesis

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Several new organic transformations have been achieved utilizing boron halide reagents. Aryl aldehydes are conveniently converted to gem-dichloromethylbenzenes using boron trichloride. Aryl aldehydes are alkylated by alkylboron chlorides in a Grignard-like fashion to generate the corresponding arylalkanols or alkylboron chlorides. Aryl aldehydes react with divinylboron halides (generated via the haloboration of alkynes) to produce 1,5-di-halo-1,4-dienes in excellent yields.

Original languageEnglish (US)
Pages (from-to)1231-1237
Number of pages7
JournalPure and Applied Chemistry
Volume75
Issue number9
DOIs
StatePublished - Sep 1 2003

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Aldehydes
Boron
Chlorides
Gems
Alkynes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Use of organoboron halides in organic synthesis. / Kabalka, George; Wu, Zhongzhi; Ju, Y.

In: Pure and Applied Chemistry, Vol. 75, No. 9, 01.09.2003, p. 1231-1237.

Research output: Contribution to journalArticle

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